Heat Treatment of Metals

What is Heat Treatment of Metals?

Heat treatment of metals is an important process for improving the mechanical and chemical properties of metals without changing its shape. It involves heating and cooling metals in a controlled manner to produce specific desired microstructures.

Heat treatments can be used to improve the strength, ductility, toughness, fatigue resistance, corrosion resistance and wear resistance of a wide variety of metals.

 Common heat treatment processes include annealing, normalizing, hardening, and tempering. Heat treatment can also be used to relieve internal stresses and improve the machinability of a metal.

How does heat Treatment works?

Heat treatment works by controlling the heating and cooling of a metal to change its microstructure and properties. The basic steps of heat treatment are as follows:

  1. Heating: The metal is heated to a specific temperature, which depends on the type of heat treatment being performed.
  2. Holding: The metal is held at the specific temperature for a certain period of time to allow for the desired microstructural changes to occur.
  3. Cooling: The metal is cooled at a controlled rate, which depends on the type of heat treatment being performed. This step is critical in determining the final microstructure and properties of the metal.
  4. Tempering (optional): Sometimes after hardening process, metal is tempered again to improve its strength and ductility balance.
heat-treatable

Different heat treatment processes use different combinations of heating and cooling rates to achieve specific properties.

For example, in annealing, the metal is heated to a high temperature and then cooled slowly to reduce hardness and increase ductility.

In contrast, in hardening, the metal is heated to a high temperature and then cooled quickly to increase hardness and strength.

Types of Heat Treatment for Metals

Types of Heat Treatment processes

Through the heat treatment process, it is possible to increase the strength, hardness, ductility, and fatigue resistance of metals. Different types of heat treatments are available that depend on the type of metal being treated.

The main types of heat treatment processes used in Engineering application are:

  • Annealing
  • Normalizing
  • Hardening
  • Tempering
  • Quenching
  • Case hardening
  • Austempering
  • Martempering
  • Carburizing
  • Nitriding
  • Carbonitriding
  • Induction hardening
  • Flame hardening
  • Vacuum heat treatment
  • Ion Nitriding
  • Solution heat treatment
  • Precipitation hardening
  • Age hardening
  • Stress Relieving
  • Isothermal Annealing
  • Controlled Rolling
Heat-treatment-on-Fe-C-diagram

What is Annealing Heat Treatment?

Annealing is a heat treatment process that is used to soften a metal by heating it to a high temperature and then cooling it slowly.

The purpose of annealing is to relieve internal stresses, refine the microstructure, improve ductility and toughness, and make the metal easier to work with.

Types of Annealing Heat Treatment Process

There are several types of annealing:

  1. Full Annealing: The metal is heated to a high temperature, typically above the upper critical temperature, and then cooled slowly. This process results in a relatively soft and ductile metal.
  2. Process Annealing: The metal is heated to a temperature below the upper critical temperature and then cooled slowly. This process is used to relieve internal stresses and improve machinability.
  3. Spheroidizing Annealing: The metal is heated to a temperature below the upper critical temperature and then cooled very slowly. This process is used to produce a spheroidal or globular microstructure, which improves ductility and toughness.
  4. Isothermal Annealing: The metal is held at a constant temperature for a period of time, and then cooled slowly. This process is used to improve the microstructure of certain alloys.
See also  Lack of Fusion vs Lack of Penetration

The annealing process is typically used on ferrous and non-ferrous metals such as steel, aluminum, copper, brass, and bronze.

The specific temperature, time, and cooling rate used in the annealing process will vary depending on the type of metal and the desired properties.

Read more: Annealing vs Normalizing

Advantages and disadvantages of Annealing Heat Treatment

Advantages of Annealing Heat Treatment:

  1. Improves ductility: Annealing increases the ductility of a metal, making it easier to bend and shape without breaking.
  2. Reduces hardness: Annealing reduces the hardness of a metal, making it easier to work with and less prone to cracking or breaking.
  3. Relieves internal stresses: Annealing can relieve internal stresses that have built up in a metal due to cold working or welding, which can prevent the metal from warping or cracking.
  4. Improves machinability: Annealing can improve the machinability of a metal, making it easier to cut, drill, or grind.
  5. Improves corrosion resistance: Annealing can improve the corrosion resistance of certain metals, as it can remove impurities and homogenize the microstructure.

Disadvantages of Annealing Heat Treatment:

  1. Time-consuming: Annealing can be a time-consuming process, especially if the metal needs to be cooled slowly.
  2. Costly: Annealing requires specialized equipment and a controlled environment, which can be costly.
  3. Changes in properties: Annealing can cause a change in properties such as strength, hardness, and corrosion resistance, which could be detrimental depending on the intended use of the metal.
  4. Not suitable for all metals: Annealing may not be suitable for all metals, as it can cause certain metals to become brittle or lose their strength.
  5. Can cause distortion: Annealing can cause distortion if proper precautions are not taken, such as clamping the metal to prevent warping.

What is Normalizing Heat Treatment?

Normalizing is a heat treatment process that is used to improve the microstructure and mechanical properties of a metal. It is similar to annealing, but the metal is cooled in air rather than being cooled slowly.

The process of normalizing involves heating the metal to a high temperature, typically above the upper critical temperature, and then allowing it to cool in still air.

This cooling rate is faster than in annealing, resulting in a harder and stronger metal. The faster cooling rate also causes the formation of a more homogeneous and fine-grained microstructure.

Annealing vs Normalizing-microstructure

The process of normalizing is typically used on ferrous metals such as steel and cast iron. Normalizing can also be used as a preparatory step before other heat treatment processes such as hardening, quenching, and tempering.

Advantages and disadvantages of Normalizing Heat Treatment

Advantages of Normalizing Heat Treatment:

  1. Improves mechanical properties: Normalizing improves the mechanical properties of a metal, such as strength, hardness, and toughness.
  2. Refines microstructure: Normalizing refines the microstructure of a metal, resulting in a more homogeneous and fine-grained structure.
  3. Relieves internal stresses: Normalizing can relieve internal stresses that have built up in a metal due to casting, welding, or cold working, which can prevent the metal from warping or cracking.
  4. Improves machinability: Normalizing can improve the machinability of a metal, making it easier to cut, drill, or grind.
  5. Improves surface finish: Normalizing can improve the surface finish of a metal, making it less prone to cracking or breaking.
  6. Improves dimensional stability: Normalizing can improve the dimensional stability of a metal, making it less likely to warp or crack during further processing.
See also  Welding Joint Efficiency

Disadvantages of Normalizing Heat Treatment:

  1. Time-consuming: Normalizing can be a time-consuming process, especially if the metal needs to be cooled slowly.
  2. Costly: Normalizing requires specialized equipment and a controlled environment, which can be costly.
  3. Changes in properties: Normalizing can cause a change in properties such as strength, hardness, and corrosion resistance, which could be detrimental depending on the intended use of the metal.
  4. Not suitable for all metals: Normalizing may not be suitable for all metals, as it can cause certain metals to become brittle or lose their strength.
  5. Can cause distortion: Normalizing can cause distortion if proper precautions are not taken, such as clamping the metal to prevent warping.

What is Hardening?

Hardening is a heat treatment process that is used to increase the hardness and strength of a metal.

It is typically used on ferrous metals such as steel and cast iron, but can also be applied to non-ferrous metals such as aluminum and brass.

The process of hardening involves heating the metal to a high temperature, typically above the upper critical temperature, and then cooling it quickly.

This rapid cooling rate, known as quenching, causes the formation of a harder and stronger microstructure.

Types of hardening processes

There are several types of hardening processes:

  1. Oil Quenching: The metal is heated to the desired temperature and then quenched in oil. This is one of the most common methods of hardening and is used for a wide variety of metals.
  2. Water Quenching: The metal is heated to the desired temperature and then quenched in water. This method is used for high carbon steels and produces a very hard and brittle microstructure.
  3. Gas Quenching: The metal is heated to the desired temperature and then quenched in a gas such as nitrogen or argon. This method is used for specialized applications and produces a very hard and brittle microstructure.
  4. Induction hardening: This is a localized hardening process where an alternating current is passed through a coil to generate an electromagnetic field. The metal piece is then inserted into the coil, heating it to a high temperature, and then quenched. This method is used for small or complex parts and can achieve a very hard and uniform surface hardness.

After hardening, the metal is typically tempered to improve its toughness and ductility. Hardening can significantly increase the strength and wear resistance of a metal, but it also makes it more brittle and less ductile

What is Quenching & Tempering Heat Treatment?

Quenching and tempering is a two-step heat treatment process that is used to improve the mechanical properties of a metal, particularly ferrous metals such as carbon steel and low alloy steel.

The first step, quenching, involves heating the metal to a high temperature and then rapidly cooling it, typically by immersing it in oil, water, or air. This rapid cooling causes the formation of a hard and strong microstructure known as martensite.

what-is-tempering

The second step, tempering, involves heating the quenched metal to a lower temperature, typically between 150-700°C depending on the desired properties and the type of steel, and then allowing it to cool slowly.

This process causes the formation of small amounts of a softer, more ductile microstructure called tempered martensite. This tempered martensite has a balance of strength and toughness that makes it suitable for many applications.

Quenching and tempering can be used to improve the mechanical properties of a metal such as strength, hardness, and toughness.

See also  What is Resistance Spot welding?

It also increases the wear resistance of the metal and also improves the dimensional stability of the metal, making it less likely to warp or crack during further processing. However, the process can also make the metal more brittle and less ductile.

What is Austempering and Martempering Heat Treatment?

Austempering is a process that involves heating the metal to a high temperature, typically above the upper critical temperature, and then quenching it into a liquid medium that is maintained at a constant temperature, called an isothermal quenching.

This process results in the formation of a microstructure called bainite, which is a combination of ferrite and cementite. Bainite has a balance of strength and toughness, which makes it suitable for many applications.

Martempering, also known as Marquenching, is a process that involves heating the metal to a high temperature, typically above the upper critical temperature, and then quenching it into a liquid medium that is maintained at a temperature slightly above room temperature, called a non-isothermal quenching.

This process results in the formation of a microstructure called martensite, which is very hard and brittle. The metal is then tempered to improve its toughness and ductility.

What is Carburizing?

Carburizing is a heat treatment process that is used to increase the carbon content of the surface of a ferrous metal.

The process involves heating the metal to a high temperature, typically between 900-950°C, in the presence of a carbon-rich atmosphere or a carbon-rich compound such as gas, liquid, or a solid.

The carbon diffuses into the surface of the metal, forming a hardened, wear-resistant surface layer known as the case.

Carburizing can be done by several methods, the most common ones are:

  • Gas Carburizing: The metal is heated in a sealed chamber that contains a carbon-rich gas such as methane or propane.
  • Liquid Carburizing: The metal is heated in a sealed chamber that contains a carbon-rich liquid such as salt bath or oil bath.
  • Pack Carburizing: The metal is packed with a carbon-rich compound such as charcoal or carbon powder and then heated.

The depth of the case and the final carbon content can be controlled by varying the temperature, time, and carbon potential of the atmosphere or compound used. Carburizing is typically followed by a process called quenching, which hardens the case and the core of the metal.

What is Nitriding?

Nitriding is a heat treatment process that is used to increase the surface hardness and wear resistance of metals.

The process involves heating the metal in an atmosphere that contains nitrogen, typically at a temperature between 500-550°C. The nitrogen diffuses into the surface of the metal, forming a hardened, wear-resistant surface layer known as the Nitride case.

There are several methods of Nitriding, the most common ones are:

  • Gas Nitriding: The metal is heated in a sealed chamber that contains a nitrogen-rich gas such as ammonia or nitrogen.
  • Ion Nitriding: The metal is heated in a sealed chamber and bombarded with nitrogen ions.

The depth of the Nitride case and the final nitrogen content can be controlled by varying the temperature, time, and nitrogen potential of the atmosphere or compound used.


Material Welding is run by highly experienced welding engineers, welding trainers & ASNT NDT Level III bloggers. We strive to provide most accurate and practical knowledge in welding, metallurgy, NDT and Engineering domains.