What is Austenitic Stainless Steel

Austenitic Stainless steel is one of the most widely used materials in various industries (more than 65% out of all stainless-steel types), including construction, food processing, and transportation, among others.

Among the various types of stainless steel, austenitic stainless steel is one of the most popular.

In this article, we will discuss what austenitic stainless steel is, its common grades, properties, and applications.

What is Austenitic Stainless Steel?

Austenitic stainless steel is a type of stainless steel that is composed of austenite, a face-centered cubic crystal structure.

It contains a high amount of chromium and nickel, which gives it excellent corrosion resistance and makes it non-magnetic.

Additionally, it has good formability, weldability, and high-temperature strength.

Austenitic stainless steels have a nickel content, which is usually 8% or higher. By adding nickel and/or molybdenum, a chrome steel becomes an austenitic steel. 

They got their name because of the austenitic structure.

Due to the advantageous composition of alloying elements, an excellent combination of corrosion resistance, ductility and toughness is achieved.

Therefore, they represent a wide range of applications, from household appliances to the food, chemical or mechanical engineering industries.

Austenitic steels are also known as chromium-nickel steels because their main alloying elements are chromium and nickel.

The minimum content of chromium is 13.5%, whereby values such as 14% or 16% can also be found in many grades.

Common Austenitic Stainless Steel Grades

There are many grades of austenitic stainless steel, each with slightly different compositions and properties. Below are some of the most common grades:

Grade 201 Stainless Steel

Grade 201 stainless steel (UNS Number: S20100) is a low-cost alternative to 304 stainless steel and is often used in decorative applications.

It has a higher manganese content than other austenitic stainless steels, which provides increased strength and ductility.

Chemical composition:

  • Chromium: 16-18%
  • Nickel: 3.5-5.5%
  • Manganese: 5.5-7.5%
  • Silicon: 1.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.25% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.060 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 260 MPa (38 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • Decorative applications
  • Household items
  • Automotive trim

Grade 202 Stainless Steel

Grade 202 stainless steel (UNS Number: S20200) is similar to grade 201 stainless steel but has a higher chromium content.

It is often used in applications where corrosion resistance is not critical, such as in cookware and utensils.

Chemical composition:

  • Chromium: 17-19%
  • Nickel: 4-6%
  • Manganese: 7.5-10%
  • Silicon: 1.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.25% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.060 max.

Mechanical properties:

  • Ultimate tensile strength: 620 MPa (90 Ksi) minimum.
  • Yield strength: 260 MPa (38 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 241 HBW

Applications:

  • Cookware and utensils
  • Decorative applications

Grade 301 Stainless Steel

Grade 301 stainless steel (UNS Number: S30100) is a high-strength austenitic stainless steel that is often used in applications that require high strength and ductility.

It has a lower nickel content than other austenitic stainless steels, which makes it more affordable.

Chemical composition:

  • Chromium: 16-18%
  • Nickel: 6-8%
  • Silicon: 1.0% max
  • Manganese: 2.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • Springs
  • Structural components
  • Automotive trim

Grade 302 Stainless Steel

Grade 302 stainless steel (UNS Number: S30200) is a variant of grade 304 stainless steel with a higher carbon content, which provides increased strength and hardness.

It is often used in applications that require high strength and corrosion resistance.

Chemical composition:

  • Chromium: 17-19%
  • Nickel: 8-10%
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 201 HBW

Applications:

  • Springs
  • Fasteners
  • Surgical instruments
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Grade 304:

This is the most common austenitic stainless steel (UNS Number: S30200) and is often referred to as “18-8” stainless steel because it contains 18% chromium and 8% nickel.

It has a low carbon content, making it resistant to sensitization and carbide precipitation during welding. Grade 304 also exhibits good corrosion resistance and excellent formability and weldability.

Chemical composition:

  • Chromium: 17-19%
  • Nickel: 8-10%
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 201 HBW

Applications:

  • Kitchen equipment
  • Food processing equipment
  • Chemical containers Heat exchangers
  • architectural applications

Related Reading: Welding Guidelines for 304 Stainless Steel.

Grade 309 Stainless Steel

Grade 309 stainless steel (UNS Number: S30908) is a high-temperature austenitic stainless steel that is often used in high-temperature applications.

It has a higher chromium and nickel content than other austenitic stainless steels, which provides increased strength and corrosion resistance at high temperatures.

Chemical composition:

  • Chromium: 22-24%
  • Nickel: 12-15%
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.08% max
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • Furnace parts
  • Heat exchangers

Grade 310 Stainless Steel

Grade 310 stainless steel (UNS Number: S30200) is a high-temperature austenitic stainless steel that is often used in applications that require high resistance to oxidation and corrosion at high temperatures. It has a high chromium and nickel content, which provides excellent corrosion resistance and strength at elevated temperatures.

Grade 310 Stainless is available in different grades as:

  1. SS310
  2. SS310S
  3. SS310H
  4. SS310Cb
  5. SS310HCb
  6. SS310MoLN

Chemical composition of Grade 310S:

  • Chromium: 24-26%
  • Nickel: 19-22%
  • Silicon: 1.50% max
  • Manganese: 2.0% max
  • Carbon: 0.108% max
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • Furnace parts
  • Heat exchangers
  • Thermal processing equipment

Related Reading: Welding Guidelines for 310 Stainless Steel.

Grade 316:

This grade is similar to 304 but with the addition of 2-3% molybdenum, which improves its corrosion resistance, particularly in chloride environments. It is often used in marine applications and medical implants.

Grade 316 stainless steel (UNS Number: S30200) is a molybdenum-bearing austenitic stainless steel that has improved resistance to corrosion compared to 304 stainless steel.

Grade 316 has a higher nickel content of 10-14% and a lower carbon content, making it more resistant to corrosion in high-temperature environments. Grade 316 also exhibits excellent formability and weldability.

Chemical composition:

  • Chromium: 16-18%
  • Nickel: 10-14%
  • Molybdenum: 2-3%
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.08% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • Chemical and pharmaceutical processing equipment
  • Marine applications
  • Medical devices
  • Heat exchangers.

Related Reading: Welding Guidelines for 316 Stainless Steel.

Grade 317 Stainless Steel

Grade 317 stainless steel (UNS Number: S30200) is a high-alloy austenitic stainless steel that contains molybdenum and higher levels of nickel and chromium than other austenitic stainless steels.

It has excellent corrosion resistance and high strength, making it suitable for use in high-temperature and corrosive environments.

Chemical composition:

  • Chromium: 18-20%
  • Nickel: 11-15%
  • Molybdenum: 3-4%
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.08% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 35% minimum.
  • Hardness: 217 HBW

Applications:

  • Chemical processing equipment
  • Power generation equipment
  • Pharmaceutical equipment

Grade 321:

Grade 321 stainless steel (UNS Number: S30200) is a stabilized austenitic stainless steel that contains titanium, which provides stabilization against sensitization (chromium carbide precipitation) and intergranular corrosion.

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Grade 321 has a higher carbon content compared to 304 and 316 stainless steel, making it more resistant to high-temperature environments. It is often used in high-temperature applications such as aircraft exhaust systems.

Chemical composition:

  • Chromium: 17-19%
  • Nickel: 9-12%
  • Titanium: Ti 5 × (C + N) min, 0.70 max
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.08% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 217 HBW

Applications:

  • High-temperature chemical and processing equipment
  • Aircraft exhaust manifolds
  • Thermal oxidizers.

Related Reading: Welding Guidelines for 321 Stainless Steel.

Grade 347:

This grade is similar to 321 but with the addition of columbium, which improves its high-temperature strength. It is often used in applications that require high-temperature resistance, such as furnace parts and jet engine components.

Grade 347 stainless steel (UNS Number: S30200) is a stabilized austenitic stainless steel that contains niobium, which provides stabilization against sensitization and intergranular corrosion.

Grade 347 stainless steel has a higher resistance to corrosion compared to grade 321 stainless steel, making it suitable for high-temperature environments.

Chemical composition:

  • Chromium: 17-19%
  • Nickel: 8-10%
  • Niobium (Cb): Cb 10 × C min, 1.00 max
  • Silicon: 0.75% max
  • Manganese: 2.0% max
  • Carbon: 0.15% max
  • Nitrogen: 0.10% max.
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 515 MPa (75 Ksi) minimum.
  • Yield strength: 205 MPa (30 Ksi) minimum.
  • Elongation: 40% minimum.
  • Hardness: 201 HBW

Applications:

  • High-temperature chemical and processing equipment
  • Aircraft exhaust manifolds
  • Thermal oxidizers.

Related Reading: Welding Guidelines for 347 Stainless Steel.

Grade 904L:

904L grade (UNS Number: N08904) contains a high amount of molybdenum and is often used in chemical processing and oil refining equipment due to its excellent corrosion resistance.

Chemical composition:

  • Chromium: 19-23%
  • Nickel: 23-28%
  • Silicon: 1.0% max
  • Manganese: 2.0% max
  • Carbon: 0.20% max
  • Nitrogen: 0.10% max.
  • Copper: 1-2%
  • Sulfur: 0.030 max
  • Phosphorus: 0.045 max.

Mechanical properties:

  • Ultimate tensile strength: 490 MPa (71 Ksi) minimum.
  • Yield strength: 220 MPa (31 Ksi) minimum.
  • Elongation: 35% minimum.
  • Hardness: Not specified.

Applications:

  • High-temperature chemical and processing equipment
  • Aircraft exhaust manifolds
  • Thermal oxidizers.

Related Reading: Welding Guidelines for 904L Stainless Steel.

Austenitic Stainless Steel Microstructure

The austenitic microstructure is characterized by a homogeneous and isotropic distribution of atoms in the crystal lattice, with a high degree of interstitial voids that allow for the easy diffusion of atoms within the material.

This microstructure is also non-magnetic, which makes it ideal for applications where magnetism could interfere with the function of the component.

The austenitic stainless steel microstructure is typically achieved through a process called solid solution strengthening, in which the nickel and chromium atoms are dissolved into the iron matrix at high temperatures.

This process results in a material with a high degree of ductility, excellent corrosion resistance, and good mechanical properties.

Properties of Austenitic Stainless Steel

The properties of austenitic stainless steel are as follows:

Corrosion resistance: Austenitic stainless steel has excellent corrosion resistance, particularly against pitting and crevice corrosion.

Non-magnetic: Due to its high nickel content, austenitic stainless steel is non-magnetic.

Formability: It has good formability and can be easily formed into complex shapes.

Weldability: Austenitic stainless steel is highly weldable and can be welded using various welding techniques.

High-temperature strength: It has good high-temperature strength and can withstand high temperatures without losing its strength.

Applications of Austenitic Stainless Steel

Due to its excellent corrosion resistance and other properties, austenitic stainless steel is used in various applications, including:

Kitchen equipment: Stainless steel appliances, sinks, and countertops are often made of austenitic stainless steel due to its corrosion resistance and ease of cleaning.

Chemical processing equipment: Austenitic stainless steel is often used in chemical processing equipment due to its corrosion resistance to various chemicals.

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Medical implants: Due to its non-magnetic properties and corrosion resistance, austenitic stainless steel is often used in medical implants.

Transportation: Many parts of cars, trucks, and airplanes are made of austenitic stainless steel due to its high-temperature strength and corrosion resistance.

Architectural applications: Austenitic stainless steel is often used in architectural applications such as handrails, elevator doors, and building facades due to its corrosion resistance and aesthetic appeal.


FAQS

Q: What are austenitic stainless steels?

A: Austenitic stainless steels are a type of stainless steel alloy that contains high levels of chromium, nickel, and sometimes other elements such as molybdenum and nitrogen.
They are non-magnetic, highly corrosion-resistant, and can be easily formed and welded.

Q: What are the benefits of using austenitic stainless steels?

A: Austenitic stainless steels have a number of benefits, including high corrosion resistance, excellent toughness and ductility, ease of fabrication, and good high-temperature strength. They are also biocompatible and often used in medical and dental applications.

Q: What are some common applications for austenitic stainless steels?

A: Austenitic stainless steels are used in a wide range of applications, including construction, food processing and packaging, chemical processing, medical and dental equipment, and automotive parts.
They are also often used in household appliances such as refrigerators, dishwashers, and washing machines.

Q: What is the difference between 304 and 316 austenitic stainless steels?

A: Both 304 and 316 austenitic stainless steels are popular choices for many applications due to their high corrosion resistance and ease of fabrication.
However, 316 contains higher levels of molybdenum and nickel than 304, making it more resistant to corrosion in certain environments, such as those with higher levels of chlorides.

Q: Can austenitic stainless steels be welded?

A: Yes, austenitic stainless steels can be easily welded using common welding methods such as TIG, MIG, and stick welding. However, the welding process can cause changes in the material’s microstructure and properties, so it is important to use appropriate techniques and procedures to ensure the weld quality and avoid issues such as corrosion or cracking.

Q: How can austenitic stainless steels be protected from corrosion?

A: Austenitic stainless steels have a natural passive layer of chromium oxide that provides corrosion resistance. However, this layer can be damaged or depleted in certain environments, such as those with high levels of chlorides or sulfuric acid.
To protect the material from corrosion, coatings such as paints or epoxy can be applied, or the material can be electropolished to restore the passive layer. Additionally, using higher alloyed austenitic stainless steels or duplex stainless steels can provide even higher corrosion resistance.

Q: Are austenitic stainless steels magnetic?

A: No, austenitic stainless steels are generally non-magnetic. However, they can become weakly magnetic after cold working or when exposed to high temperatures for extended periods of time.

Q: What is the temperature range for austenitic stainless steels?

A: Austenitic stainless steels can typically be used in a wide temperature range, from cryogenic temperatures up to around 800-900°C (1472-1652°F) depending on the specific alloy and application. At higher temperatures, however, the material can experience reduced strength and oxidation resistance.

Q: Can austenitic stainless steels be hardened by heat treatment?

A: Austenitic stainless steels are generally not hardened by heat treatment like martensitic or ferritic stainless steels. Instead, their properties can be modified by cold working or through the addition of certain elements such as nitrogen or carbon. Some high-nickel austenitic stainless steels can also be strengthened through precipitation hardening.

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